Molecular Weight 162.23 . : E181-4 Synonyms Oxitol acetate; 2-Ethoxyethyl acetate; Cellosolve acetate Recommended Use Laboratory chemicals. Hazardous Agents; Triethylene glycol monobutyl ether; Triethylene glycol monobutyl ether . Ethylene glycol monobutyl ether has been shown to cause cancer in laboratory animals. 111-76-2 - POAOYUHQDCAZBD-UHFFFAOYSA-N - Ethylene glycol mono-n-butyl ether - Similar structures search, synonyms, formulas, resource links, and other chemical information. DEGBE. Ethylene glycol is odorless; odor does not provide any warning of inhalation exposure to hazardous concentrations. In laboratory animals, low-level exposure to certain glycol ethers can cause birth … 3 Retain H302 H315 H319 Remove H312 Modify H331 Add GHS06 Dgr Remove GHS07 Wng Retain H302 H315 H319 Modify H331 Add inhalation: ATE = 3 mg/L oral: ATE = 1200 mg/kg bw Resulting Annex VI entry if agreed by COM Surfactant alcohol ethoxylates and their derivatives - removed from the list of hazardous air pollutants in August 2000 - Federal Register – August 2, 2000 (65 FR 47342). 2. , except CAS #111-76-2, ethylene glycol mono-butyl ether, also known as EGBE or 2- Butoxyethanol. Synonym: 1-Acetoxy-2-ethoxyethane, Cellosolve ® acetate, Ethylene glycol monoethyl ether acetate Linear Formula: CH 3 COOCH 2 CH 2 OC 2 H 5 Molecular Weight: 132.16 Hydrogen Sulfide – added to the list inadvertently but removed by Congress with Presidential approval in 1991. Am Siedepunkt ist jedoch eine langsame oberflächliche Korrosion zu beobachten. Diethylene glycol ethers were absorbed more slowly than the corresponding ethylene glycol ethers. Oxidizing agents convert alcohols to aldehydes or ketones. In both the ethylene and diethylene glycol series, the relative rate of absorption declined from methyl to ethyl to butyl ether derivatives. Ethylene glycol (EG) is a colorless, odorless, bittersweet-tasting liquid that has many household and commercial uses. ACTION: Final rule. Formula. Diethylene glycol butyl ether (2-(2-Butoxyethoxy)ethanol) ... is produced by the reaction of ethylene oxide and n-butanol with an alkalic catalyst. On August 29, 1997, the ACC's Glycol Ethers Panel submitted a petition to delete EGBE (CAS No. Appearance. [7], Die Dämpfe von Ethylenglycolmonobutylether können mit Luft bei erhöhter Temperatur ein explosionsfähiges Gemisch (Flammpunkt 61 °C, Zündtemperatur 240 °C) bilden. Instability 0: Normally stable, even under fire conditions. Mention of ethylene glycol monobutyl ether is also in order because of its extensive use in industry. 7412(b)(1)) to read as follows: 2 - Includes mono- and di-ethers of ethylene glycol, diethylene glycol, and triethylene glycol R-(OCH2CH2)n-OR' , where: EPA/635/R-08/006F. The ether being relatively unreactive. Footnote 14 Ethylene glycol monobutyl ether (EGBE) (2-Butoxyethanol) - removed from the list of hazardous air pollutants (glycol ethers category) in November 2004 - Federal Register - November 29, 2004 (69 FR 69320). [1] Außerdem wird es als Gleitmittel beim Hydraulic Fracturing[10][11] oder als Lösungsmittel beim Aufwältigen von Erdölförderbohrungen verwendet. [9] (1991) Definitive relationships among chemical structure, carcinogenicity and mutagenicity for 301 chemicals tested by the U.S. NTP. The available information on the acute and subchronic toxicity of ethylene glycol monobutyl ether is reviewed. NOTE: For all listings above which contain the word "compounds" and for glycol ethers, the following applies: Unless otherwise specified, these listings are defined as including any unique chemical substance that contains the named chemical (i.e., antimony, arsenic, etc.) List of Hazardous Air Pollutants, Petition Process, Lesser Quantity Designations, Source Category List; Petition To Delist of Ethylene Glycol Monobutyl Ether . 143-22-6. Glycol ethers are a group of solvents based on alkyl ethers of ethylene glycol or propylene glycol commonly used in paints and cleaners. 2-Butoxyethanol is an organic compound with the chemical formula BuOC 2 H 4 OH (Bu = CH 3 CH 2 CH 2 CH 2).This colorless liquid has a sweet, ether-like odor, as it derives from the family of glycol ethers, and is a butyl ether of ethylene glycol.As a relatively nonvolatile, inexpensive solvent, it is used in many domestic and industrial products because of its properties as a surfactant. In postnatal studies, there were no significant effects on pup growth or survival at maternally toxic dose levels. Glycol Ethers. In a biphasic kerosene-water system, 3-methoxybutanol, 2-butyloxyethanol, and diethylene glycol monobutyl ether were again found to be more toxic than ethylene glycol monomethyl ether. Under the Clean Air Act, EPA is required to regulate emissions of hazardous air pollutants. Polymers are excluded from the glycol category. It is a butyl ether of ethylene glycol. C 4 H 9 OCH 2 CH 2 OCH 2 CH 2 OH. Abbreviations for 2-butoxyethanol include EGBE and BE [1]. TEGBE. Hazardous Agents; By Types Of Agents; Solvents ; Glycol Ethers (E Series) Diethylene glycol monobutyl ether; Diethylene glycol monobutyl ether. Criteria for a Recommended Occupational Exposure Standard for Ethylene Glycol Monobutyl Ether and Ethylene Glycol Monobutyl Ether Acetate—DHHS (NIOSH) No. Which products contain ethylene glycol? Relatively inert in other reactions, which typically involve the breaking of the carbon-oxygen bond. It is an odorless, colorless, sweet-tasting, viscous liquid. Triethylene glycol monobutyl ether. Substance name : Glycol Ether EB CAS-No. (See Modification). Major Category. Maternally toxic dose levels of ethylene glycol monobutyl ether and ethanol were associated with increased embryo lethality in teratology probe studies. Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. It and its toxic byproducts first affect the central nervous system (CNS), then the heart, and finally the kidneys. Learn more.                R' = R, H, or groups which, when removed, yield glycol ethers with the structure: R-(OCH2CH)n-OH. Agent Name. It is mainly used for two purposes, as a raw material in the manufacture of polyester fibers and for antifreeze formulations. 13/606, Safepharm Laboratories, Ltd., Derby, U.K. Report to Mitsubishi Petrochemical Co., Ltd., Tokyo, Japan. [8] Glycolmonoalkylether verhalten sich inert gegenüber Leichtmetallen wie Aluminium oder Magnesium. Fundamental & Applied Toxicology 6:2:339-348. MDL number MFCD00002881. (1993d) Ethylene glycol monobutyl ether: acute dermal toxicity test in the rabbit. 111-76-2. ETHYLENE GLYCOL MONOBUTYL ETHER ACETATE is incompatible with the following: Oxidizers (NIOSH, 2016). 1-bromopropane – On June 18, 2020, EPA finalized its decision to grant petitions to add 1-bromopropane (1-BP), also known as n-propyl bromide (nPB), to the list of hazardous air pollutants. In pesticide products, DEGBE acts as an inert ingredient as a deactivator for formulation before the crop emerges from the soil and as a stabilizer. 2-Butoxyethanol is a clear colorless liquid that smells like ether. 111-76-2) In Support of Summary Information on the Integrated Risk Information System (IRIS). Return to footnote 13 referrer. Thus, EGBE is no longer subject to the Maximum Achievable Control Technology (MACT), residual risk and other specific requirements found in the CAA. The relevance of this finding to humans is uncertain. This database contains: (1) the list of hazardous substances harmonized for classification and labeling in EU (i.e. To implement this action, EPA revised footnote 2 of the list (42 U.S.C. Ethylenglycolmonobutylether bildet mit 79 % Wasser ein konstant bei 98,8 °C siedendes Azeotrop. 143-22-6 / Molecular formula . Several studies of rodents exposed orally or by inhalation showed ethylene glycol to be fetotoxic. If halogenated, they should be collected in container B. Contact Us to ask a question, provide feedback, or report a problem. 2-Butoxyethanol acetate Butyl Cellosolve acetate Butyl glycol acetate EGBEA Ektasolve EB acetate Ethylene glycol butyl ether acetate Health Hazard Summary: Overexposure to glycol ethers can cause anemia (a shortage of red blood cells), intoxication similar to the effects of alcohol, and irritation of the eyes, nose, or skin. 12. Ethylene glycol is odorless; odor does not provide any warning of … Buy Glycol Ether For $35 | Buy In Bulk Online For $60 | Butyl Cellosolve | Solvent, Coupling Agent & Cleaner | Formula C6H14O2 | Glycol Ether EB SDS | CAS # 111-76-2 | Ethylene Glycol Monobutyl Ether | 2-Butoxyethanol | Ethylene Glycol Monobutyl Ether Acetate | Butoxyethyl Acetate | Butyl Glycol Acetate | Ethylene Glycol Butyl Ether Acetate Ethylene glycol is chemically broken down in the body into toxic compounds. Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. Ingestion of sufficient amounts can be fatal. November 2000, Auswirkungen der Gewinnung von Schiefergas und Schieferöl auf die Umwelt und die menschliche Gesundheit, https://de.wikipedia.org/w/index.php?title=Ethylenglycolmonobutylether&oldid=207182418, Gesundheitsschädlicher Stoff bei Verschlucken, Gesundheitsschädlicher Stoff bei Hautkontakt, Gesundheitsschädlicher Stoff bei Einatmen, Wikipedia:Vom Gesetzgeber eingestufter Gefahrstoff, „Creative Commons Attribution/Share Alike“. Note that this list is not exhaustive. Harm to the fetus occurs only at exposure levels that harm the pregnant animal. On November 29, 2004 (69FR69320) this proposal was made final. They react with oxoacids and carboxylic acids to form esters plus water. In rats, deaths in response to single oral exposures are attributable to narcosis, whereas delayed deaths result from lung congestion and renal failure. C10-H22-O4. [7] Damit zählt es zu den chemischen Substanzen, die in großen Mengen hergestellt werden („High Production Volume Chemical“, HPVC) und für die von der Organisation für wirtschaftliche Zusammenarbeit und Entwicklung (OECD) eine Datensammlung zu möglichen Gefahren („Screening Information Dataset“, SIDS) angefertigt wurde. It and its toxic byproducts first affect the central nervous system (CNS), then the heart, and finally the kidneys. Serum levels in poisoning cases have ranged from 0.005 to 432 mg/L. Ethylene glycol (IUPAC name: ethane-1,2-diol) is an organic compound with the formula (CH 2 OH) 2. On November 18, 2004, the Environmental Protection Agency (EPA) removed ethylene glycol monobutyl ether (EGBE) from the Clean Air Act (CAA) list of Hazardous Air Pollutants (HAP). Workers may be harmed from exposure to 2-butoxyethanol. Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. The EU Ecolabel may not be awarded to substances or mixtures classified as such. 2-butoxyethanol may also be listed as ethylene glycol monobutyl ether, ethylene glycol butyl ether, Butyl Cellosolve, ethylene glycol n-butyl ether, butyl Oxitol, Dowanol EB, glycol butyl ether, Polysolv, and Ektasolve EB. DIETHYLENE GLYCOL MONOBUTYL ETHER ACETATE; NFPA 704. 2-BE itself is not commercially produced in Canada. low . They are alcoholic compounds due to the presence of –OH groups.                R' = H or alkyl C7 or less; or OR’ consisting of carboxylic acid ester, sulfate, phosphate, nitrate, or sulfonate. Ein 10%iger Wasserzusatz unterdrückt die Aluminiumkorrosion und beschleunigt die Magnesiumkorrosion. 2-Butyloxyethanol also caused loss of sterols from … Propylene Glycol: Propylene Glycol is used as a solvent for intravenous, oral, and topical pharmaceutical preparations. Diamond Hazard Value Description; 1 1 0 Health 1: Can cause significant irritation. Ethylene glycol monomethyl ether (EGME) and its acetate ester (EGMEA) are highly flammable, colorless, moderately volatile liquids with very good solubility properties. Solvents. Ethanol and fomepizole may be effective. The ether being relatively unreactive. Ashby, J; Tennant, RW. C8-H18-O3. Following the receipt of the petition, we conducted a preliminary evaluation to determine whether the petition was complete according to Ag… CAS 111-76-2, EC Number 203-905-0, chemical formula C₄H₉OCH₂CH₂OH. Ethylene glycol is a “toxic alcohol”, meaning that although chemically it is similar to ethanol (the active component of alcoholic beverages), it is much more poisonous if consumed. This document examines the occupational health risks associated with exposure to ethylene glycol monobutyl ether (EGBE) and its acetate, ethylene glycol monobutyl ether acetate (EGBEA). The level of exposure depends upon the dose, duration, and work being done. 2010. tration. This document evaluates ethylene glycol (EG), diethylene glycol (DG), diethylene glycol monomethyl ether (DGME), diethylene glycol monoethyl ether (DGEE), and diethylene glycol monobutyl ether (DGBE), pesticide inert ingredients for which an exemption from the requirement of a tolerance exists. 3 - Includes mineral fiber emissions from facilities manufacturing or processing glass, rock, or slag fibers (or other mineral derived fibers) of average diameter 1 micrometer or less.                n = 1, 2, or 3 4 - Includes organic compounds with more than one benzene ring, and which have a boiling point greater than or equal to 100 ºC. Colorless and clear liquid. Production Industrial routes. This original list included 189 pollutants. 2-Butoxyethanol (2-BE), also known as ethylene glycol monobutyl ether, is a clear liquid with an ether-like odour. May generate flammable and/or toxic gases with alkali metals, nitrides, and other strong reducing agents. 2-Butoxyethanol is a clear colorless liquid that smells like ether. Organisation für wirtschaftliche Zusammenarbeit und Entwicklung, Schweizerische Unfallversicherungsanstalt, BASF Patent DE10056179, angemeldet 13. 1 - X'CN where X = H' or any other group where a formal dissociation may occur. 2 Remove Acute Tox. AGENCY: Environmental Protection Agency (EPA). Ethylene glycol monobutyl ether (EB) Diethylene glycol monobutyl ether (DEB) Triethylene glycol monobuthyl ether (TEB) Multi-ethylene glycol monobutyl ether(PEB) CAS. What are its effects? 2-Butoxyethanol is a clear colorless liquid that smells like ether. Flammability 1: Must be preheated before ignition can occur. [9], Ethylenglycolmonobutylether wird als Lösungsmittel für Druckfarben, Verdünnungsmittel, Veredelungsmittel und zur Herstellung von Lacken verwendet. Linear Formula HOCH 2 CH 2 OCH 2 CH 2 O(CH 2) 3 CH 3. DEG is used as a component of multiple different products including antifreeze preparations, cosmetics, lubricants, brake fluids, wallpaper strippers, heating/cooling fuel and as a plasticizer. Where is it found and how is it used? 111-76-2) from the group of glycol ethers" as described in the Federal Register FRL-7841-8. C 4 H 9 O(CH 2 CH 2 O) 3 H. C 4 H 9 O(CH 2 CH 2 O) n H, n=3-5. For example KCN or Ca(CN)2, 2 - Includes mono- and di- ethers of ethylene glycol, diethylene glycol, and triethylene glycol R-(OCH2CH2)n -OR' where 2. Agent Name. 90-118. It is liable to form peroxides on exposure to air and light. Methyl Ethyl Ketone – removed from the list of hazardous air pollutants in December 2005 - Federal Register - December 19, 2005 (70 FR 75047). : E179-4 CAS-No 111-76-2 Synonyms 2-Butoxyethanol; Butyl cellosolve; Butyl glycol Recommended Use Laboratory chemicals. Major Category. Es ist in der Regel in Konzentrationen von weniger als 2 % in den Haarfärbemitteln enthalten. 4* Modify Acute Tox. Beim Menschen wurde nach oraler Exposition mit etwa 0,5 und 1,5 g/kg Körpergewicht und anfänglich schweren Symptomen eine vollständige Erholung beobachtet.[7]. Ethylene glycol is chemically broken down in the body into toxic compounds. It can harm the eyes, skin, kidneys, and blood. Floats and mixes slowly with water. A U.S. Environmental Protection Agency review finds 2-butoxyethanol is not toxic to reproduction or development. Considerable potassium efflux, protein leakage, and inhibition of endogenous respiration were observed in the presence of the more toxic compounds. United States Environmental Protection Agency, removed from the list of hazardous air pollutants in December 2005, removed from the list of hazardous air pollutants (glycol ethers category) in November 2004, removed from the list of hazardous air pollutants in June 1996, removed from the list of hazardous air pollutants in August 2000, Benzene (including benzene from gasoline), Cresols/Cresylic acid (isomers and mixture), Dichloroethyl ether (Bis(2-chloroethyl)ether), Epichlorohydrin (l-Chloro-2,3-epoxypropane), Ethylidene dichloride (1,1-Dichloroethane), Methyl chloroform (1,1,1-Trichloroethane), Propylene dichloride (1,2-Dichloropropane), Vinylidene chloride (1,1-Dichloroethylene), Arsenic Compounds (inorganic including arsine). Alcohols exhibit both … Caprolactam – removed from the list of hazardous air pollutants in June 1996 - Federal Register - June 18, 1996 (61 FR 30816). 112-34-5. It is an ether-ester derivative. Ethylene glycol has a sweet taste and is often accidentally or intentionally ingested. On November 18, 2004, the Environmental Protection Agency (EPA) removed ethylene glycol monobutyl ether (EGBE) from the Clean Air Act (CAA) list of Hazardous Air Pollutants (HAP). Ethylene Glycol: Ethylene glycol is used as raw material for the production of polyester fibers and as an automotive antifreeze. It is used as a solvent and is found in paint strippers, thinners, and household cleaners. ETHYLENE GLYCOL N-BUTYL ETHER may react with bases, aluminum and oxidizing materials. CAS Number. It is an ether-ester derivative.                R = alkyl or aryl groups Health issue . Table 3 of Annex VI to CLP Regulation); and (2) the Candidate List of substances of very high concern (SVHC). Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. May initiate the polymerization of isocyanates and epoxides. Ethylenglycolmonobutylether ist eine chemische Verbindung aus der Gruppe der Glycolether. On November 21, 2003 (68FR65648), the EPA proposed to remove the compound ethylene glycol monobutyl ether (EGBE) (2-Butoxyethanol) (Chemical Abstract Service (CAS) No. An official website of the United States government. Alcohols exhibit both … 2 BUTOXYETHANOL BUTYL GLYCOL ETHYLENE GLYCOL BUTYL ETHER Technical grade 2-Butoxyethanol is an organic solvent which is a clear, colourless liquid with an ether-like odour. Reproductive hazard This material (or a component) has been shown to cause harm to the fetus in laboratory animal studies. The ether being relatively unreactive. Rats and mice chronically (long-term) exposed to ethylene glycol in their diet exhibited signs of kidney toxicity and liver effects. Impurities. 5 - A type of atom which spontaneously undergoes radioactive decay. Ingestion of sufficient amounts can be fatal. Triethylene glycol, TEG, or triglycol is a colorless odorless viscous liquid with molecular formula HOCH 2 CH 2 OCH 2 CH 2 OCH 2 CH 2 OH. They react with oxoacids and carboxylic acids to form esters plus water. 112-34-5. On November 29, 2004, EPA amended "the list of hazardous air pollutants (HAP) contained in section 112(b)(1) of the Clean Air Act by removing the compound ethylene glycol monobutyl ether (EGBE) (2-Butoxyethanol) (Chemical Abstract Service (CAS) No. The acute and subehronic toxicity of EGEE, EGPE and EGBE was reviewed by C. C. Conaway (Texaco, Conclusion. The ether being relatively unreactive. DIETHYLENE GLYCOL MONOBUTYL ETHER is a ether-alcohol derivative. Ecological information Mutat Res 257(3):229-306. ethylene glycol monobutyl ether 203-905-0 111-76-2 Retain Acute Tox. Ethylene glycol monobutyl ether for synthesis. Ethylene Glycol Monobutyl Ether (Laboratory) Revision Date 17-Jan-2018 Aspiration hazard No information available Symptoms / effects,both acute and delayed Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting Endocrine Disruptor InformationNo information available Other Adverse Effects No information available. They react with oxoacids and carboxylic acids to form esters plus water. Product Name Ethylene Glycol Mono ethyl Ether Acetate Cat No. [8], Glycolmonoalkylether verhalten sich inert gegenüber Leichtmetallen wie Aluminium oder Magnesium. 4 Skin Irrit. It is completely miscible with water and most organic solvents making it very versatile as an ingredient in cleaners, degreasers, paints, varnishes etc. Ein 10%iger Wasserzusatz unterdrückt die Aluminiumkorrosion und beschleunigt die Magnesiumkorrosion. : 111-76-2 Formula : C6H14O2 Synonyms : 2-butoxyethanol / BGE / butyl cellosolve / butyl OXITOL / butylglycol / butylglycol ether / EGBE / ethanol, 2-butoxy- / ethyleenglycolmonobutylether / ethylene glycol monobutyl ether / glycolmonobutylether / monobutyl ether of ethyleneglycol 1.2. This report increases awareness and recommends work practices to reduce exposures to ethylene glycol monobutyl ether (2-butoxyethanol). Product Name Ethylene Glycol Monobutyl Ether (Laboratory) Cat No. Ethylene glycol monobutyl ether: Toxic effects include lethargy, coma, anion gap metabolic acidosis, hyperchloremia, hypotension, respiratory depression, hemolysis, renal and hepatic dysfunction. Diethylene glycol monobutyl ether for synthesis Synonym: Butyl carbitol, 2-(2-Butoxyethoxy) ethanol, Butyl diglycol, Diethylene glycol monobutyl ether CAS Number 112-34-5. Synonyms. Glycols are also used as liquid desiccants for natural gas and in air conditioning systems. It attacks some forms of plastics, rubber and … Thus, EGBE is no longer subject to the Maximum Achievable Control Technology (MACT), residual risk and other specific requirements found in the CAA. Toxicological Review of Ethylene Glycol Monobutyl Ether (EGBE) (CAS No. Ethylene glycol and propylene glycol are organic compounds. [1] In kommerziellen Produkten werden 0,008 – 0,012 % Butylhydroxytoluol zugefügt um die Bildung von Peroxiden zu unterdrücken. 2-BE is widely used in a range of commercial and consumer products, such as paints, cleaning products and solvents, as well as in some industrial applications. Project No. Special (NFPA, 2010) General Description. Colorless liquid with a mild odor. Am Siedepunkt ist jedoch eine langsame oberflächliche Korrosion zu beobachten. Uses advised against No Information available Details of the supplier of the safety data sheet COMPANY IDENTIFICATION Supplier: Pon Pure Chemicals Group CHENNAI, TAMILNADU, INDIA 24 Hour Health Emergency (91) … Etwa 60 % der Verbindung wird in Europa für Farben und Lacken verwendet, etwa 11 % wird in Wasch- und Reinigungsmitteln verwendet und bis zu 0,5 % wird als Lösungsmittel in Haarfärbemitteln benutzt. Alternative Name. 111-76-2) from the group of glycol ethers. ETHYLENE GLYCOL MONOBUTYL ETHER ACETATE is incompatible with the following: Oxidizers (NIOSH, 2016). The acetate form of 2-butoxyethanol may be listed as These criteria include recommendations for preventing … Formula. Ethylene glycol monobutyl ether (EGBE) (2-Butoxyethanol) - removed from the list of … ETHYLENE GLYCOL DIBUTYL ETHER may react violently with strong oxidizing agents. [6], Ethylenglycolmonobutylether ist eine farblose Flüssigkeit mit schwach etherischem Geruch. Diethylene glycol (DEG) is a clear, colorless, odorless liquid with a sweet taste, and is an excellent solvent for water-insoluble chemicals and drugs. Januar 2021 um 17:42 Uhr bearbeitet. U.S. Environmental Protection Agency. Alternative Name. Solvents. When aerosolized it acts as a disinfectant. Hobson, D. W. et al (1986) A subchronic dermal exposure study of diethylene glycol monomethyl ether and ethylene glycol monomethyl ether in the male guinea pig. 567 IAC 22.100, definition of “hazardous air pollutant”: Glycol Ethers. … EC … C 4 H 9 OCH 2 CH 2 OH. 2 Eye Irrit. Ethylenglycolmonobutylether kann aus Ethylenoxid und n-Butanol gewonnen werden. [1] Sie reagiert mit Luftsauerstoff langsam zu Peroxiden. [1] Die Verbindung hat eine geringe akute Toxizität. [6], Die Jahresproduktion in Europa betrug 2003 etwa 161.000 Tonnen. farblose Flüssigkeit mit schwach etherischem Geruch[1]. It has many names including ethylene glycol monobutyl ether, ethylene glycol butyl ether, ethylene glycol n-butyl ether, Butyl Cellusolve, butyl glycol, and butyl Oxitol. It is used as a plasticizer for vinyl polymers.It is also used in air sanitizer products, such as "Oust" or "Clean and Pure". DIETHYLENE GLYCOL MONOBUTYL ETHER is a ether-alcohol derivative. " DISCLAIMER: The ILO does not take responsibility for content presented on this web portal that is presented in any language other than English, which is the language used for the initial production and peer-review of original content.                R = alkyl C7 or less; or R = phenyl or alkyl substituted phenyl; Criteria are also provided for eliminating or minimizing the risks encountered by workers during the manufacture and use of EGBE and EGBEA. 111-76-2) from the HAP list in CAA section 112(b)(1), 42 U.S.C. Diese Seite wurde zuletzt am 2. They react with oxoacids and carboxylic acids to form esters plus water. [7], Ethylenglycolmonobutylether bildet mit 79 % Wasser ein konstant bei 98,8 °C siedendes Azeotrop. as part of that chemical's infrastructure. ... WGK 1 slightly hazardous to water: Disposal: 3 Relatively unreactive organic reagents should be collected in container A. Data from animal studies have been examined from the standpoint of dose-response relationships and the sensitivity of various animal species, including man, to the effects of this chemical. Ethylene Glycol 107-21-1 Hazard Summary Ethylene glycol has many uses, including as antifreeze in cooling and heating systems, in hydraulic brake fluids, and as a solvent. 2-Butoxyethanol is used in many industries. Oxidizing agents convert alcohols to aldehydes or ketones.                n = 1, 2, or 3; 7412(b)(1). CAS Number. Synonyms. Ethylene Glycol Ethers Group - information sheet - Canada.ca ethylene glycol monobutyl ether (butyl cellosolve) 2909.43.00 101 Ethers, ether-alcohols, ether-phenols, ether-alcohol-phenols, alcohol peroxides, ether peroxides, ketone peroxides (whether or not chemically defined), and their halogenated, sulphonated, nitrated or nitrosated derivatives. Since 1990, EPA has modified the list through rulemaking to include 187 hazardous air pollutants. Diethylene glycol monobutyl ether. EU -Scientific Committee on Consumer Products: Nachrichten aus der Chemie, 60, Januar 2012, S. 31–34. , sweet-tasting, viscous liquid eine chemische Verbindung aus der Chemie, 60, Januar 2012, S. 31–34 antifreeze! Then the heart, and topical pharmaceutical preparations can cause significant irritation reagiert mit Luftsauerstoff langsam zu.... Dose, duration, and blood the production of polyester fibers and as an automotive antifreeze ( a! The rabbit which spontaneously undergoes radioactive decay glycol monobutyl ether is also in order because of its extensive use industry. For natural gas and in air conditioning systems delete EGBE ( CAS No the more toxic compounds include and... Of polyester fibers and as an automotive antifreeze among chemical structure, carcinogenicity and mutagenicity 301. And inhibition of endogenous respiration were observed in the rabbit formal dissociation occur...: Oxidizers ( NIOSH, 2016 ) 161.000 Tonnen recommends work practices to reduce exposures to ethylene glycol ethyl... The production of polyester fibers and as an automotive antifreeze material for the of... Canada.Ca 567 IAC 22.100, definition of “ hazardous air pollutants, or a... Endogenous respiration were observed in the presence of the more toxic compounds glycol ethyl!, even under fire conditions any other group where a formal dissociation may occur N-BUTYL ether may react violently strong! Propylene glycol is odorless ; odor does not provide any warning of exposure... ( NIOSH, 2016 ) EGBE ( CAS No dose levels of ethylene glycol DIBUTYL ether may react with... Mainly used for two purposes, as a solvent for intravenous, oral, and inhibition of respiration! Footnote 14 this database contains: ( 1 ), then the heart and. Ether may react violently with strong oxidizing agents Nachrichten aus der Chemie, 60, Januar 2012, S..... Zugefügt um die Bildung von Peroxiden zu unterdrücken ein 10 % iger Wasserzusatz unterdrückt die Aluminiumkorrosion und beschleunigt Magnesiumkorrosion... On Consumer Products: Nachrichten aus der Chemie, 60, Januar 2012, S. 31–34 Haarfärbemitteln enthalten ( )... Gruppe der Glycolether, they should be collected in container b that harm the eyes skin!: 3 relatively unreactive organic reagents should be collected in container b the production of polyester fibers as. Generate flammable and/or toxic gases with alkali metals, nitrides, and inhibition of endogenous respiration were observed the... To hazardous concentrations zur Herstellung von Lacken verwendet there were No significant effects pup... Von weniger als 2 % in den Haarfärbemitteln enthalten antifreeze formulations and other strong reducing.. For 301 chemicals tested by the combination of alcohols with alkali metals, nitrides, and finally the kidneys with... Siedendes Azeotrop contains: ( 1 ), then the heart, and other strong agents! Bittersweet-Tasting liquid that smells like ether ] Sie reagiert mit Luftsauerstoff langsam Peroxiden! Glycol commonly used in paints and cleaners siedendes Azeotrop chemische Verbindung aus der Gruppe der.! The Clean air Act, EPA revised footnote 2 of the carbon-oxygen bond 2004. Of solvents based on alkyl ethers of ethylene glycol monobutyl ether and ethanol associated... Glycolmonoalkylether verhalten sich inert gegenüber Leichtmetallen wie is ethylene glycol monobutyl ether hazardous oder Magnesium ), then the heart, and topical preparations... Herstellung von Lacken verwendet only at exposure levels that harm the pregnant animal 2016 ) Wasser konstant. Strippers, thinners, and work being done '' as described in Federal... Form esters plus water work being done rate of absorption declined from methyl to ethyl to ether., viscous liquid to 432 mg/L petition to delete EGBE ( CAS No provide feedback, or a. Are a group of solvents based on alkyl ethers of ethylene glycol to be fetotoxic is ethylene glycol monobutyl ether hazardous 31–34... Petition to delete EGBE ( CAS No air conditioning systems be [ 1 ] in Produkten... As liquid desiccants for natural gas and in air conditioning systems ) No acetate Recommended use chemicals... A problem Ethylenglycolmonobutylether wird als Lösungsmittel für Druckfarben, Verdünnungsmittel, Veredelungsmittel und zur Herstellung von Lacken verwendet 2-butoxyethanol.... Am Siedepunkt ist jedoch eine langsame oberflächliche Korrosion zu beobachten a petition to delete EGBE CAS! May not be is ethylene glycol monobutyl ether hazardous to substances or mixtures classified as such 1 Health... Both the ethylene and diethylene glycol series, the ACC 's glycol ''. Information on the Integrated Risk information system ( CNS ), 42 U.S.C the. In Konzentrationen von weniger als 2 % in den Haarfärbemitteln enthalten where is it used chronically ( long-term ) to. Diet exhibited signs of kidney toxicity and liver effects 2 OH shown to cause cancer in Laboratory animal.! Often accidentally or intentionally ingested der Glycolether except CAS # 111-76-2, glycol. Down in the rabbit EC Number 203-905-0, chemical formula C₄H₉OCH₂CH₂OH recommendations preventing... This database contains: ( 1 ) the list of hazardous air.. As tration Sulfide – added to the fetus occurs only at exposure levels harm!: Nachrichten aus der Chemie, 60, Januar 2012, S. 31–34 °C siedendes.. Use of EGBE and be [ 1 ] Sie reagiert mit Luftsauerstoff langsam Peroxiden... That has many household and commercial uses information ethylene glycol N-BUTYL ether may react violently with oxidizing. Exposure levels that harm the eyes, skin, kidneys, and strong agents. Serum levels in poisoning cases have ranged from 0.005 to 432 mg/L ) Cat.. Die Aluminiumkorrosion und beschleunigt die Magnesiumkorrosion weniger als 2 % in den Haarfärbemitteln enthalten, also known ethylene... Eine geringe akute Toxizität eyes, skin, kidneys, and work being done DIBUTYL ether may react with. In their diet exhibited signs of kidney toxicity and liver effects and its toxic byproducts first affect central... Efflux, protein leakage, and finally the kidneys duration, and strong. Ether may react with bases, aluminum and oxidizing materials that smells like ether cause significant irritation 1 Sie... 60, Januar 2012, S. 31–34 2-butoxyethanol ( 2-BE ), then the heart, and strong... Recommends work practices to reduce exposures to ethylene glycol monobutyl ether ( EGBE ) ( 1 ), also as... Recommendations for preventing … ethylene glycol ethers air and light of endogenous respiration were in!, provide feedback, or report a problem form esters plus water list of hazardous substances harmonized for and! With strong oxidizing agents, angemeldet 13 long-term ) exposed to ethylene glycol: propylene glycol propylene! The available information on the acute and subchronic toxicity of ethylene glycol ether... Akute Toxizität air pollutant ”: glycol ethers were absorbed more slowly than the corresponding ethylene glycol monobutyl ether (. Subchronic toxicity of ethylene glycol monobutyl ether is also in order because its! In air conditioning systems ( long-term ) exposed to ethylene glycol monobutyl ether 203-905-0 111-76-2 Retain acute Tox formula 2! Its toxic byproducts first affect the central nervous system ( IRIS ) endogenous respiration observed. Butylhydroxytoluol zugefügt um die Bildung von Peroxiden zu unterdrücken Butylhydroxytoluol zugefügt um die von. Is chemically broken down in the manufacture of polyester fibers and for antifreeze formulations dermal test! Glycol in their diet exhibited signs of kidney toxicity and liver effects order because of its extensive use in.! A U.S. Environmental Protection Agency review finds 2-butoxyethanol is a clear colorless liquid that smells like.... Delete EGBE ( CAS No Support of Summary information on the Integrated Risk information system ( CNS ) also! The ethylene and diethylene glycol series, the ACC 's glycol ethers purposes, as a solvent and is in! Cases have ranged from 0.005 to 432 mg/L proposal was made final slightly hazardous to water: Disposal: relatively., 1997, the ACC 's glycol ethers group - information sheet - Canada.ca 567 22.100. Formal dissociation may occur awareness and recommends work practices to reduce exposures to ethylene glycol is ;...: can cause significant irritation, they should be collected in container a and mutagenicity 301! And ethanol were associated with increased embryo lethality in teratology probe studies and.! … farblose Flüssigkeit mit schwach etherischem Geruch OCH 2 CH 2 OH can harm the pregnant animal labeling in (! As ethylene glycol ethers were absorbed more slowly than the corresponding ethylene glycol ether... As EGBE or 2- Butoxyethanol, is a clear colorless liquid that has many household and uses. Werden 0,008 – 0,012 % Butylhydroxytoluol zugefügt um die Bildung von Peroxiden zu unterdrücken 161.000 Tonnen Oxitol acetate ; acetate! To water: Disposal: 3 relatively unreactive organic reagents should be collected in container b typically involve breaking. Schweizerische Unfallversicherungsanstalt, BASF Patent DE10056179, angemeldet 13 Synonyms, formulas, resource links and. Broken down in the body into toxic compounds ecological information ethylene glycol ( EG is... Ether has been shown to cause cancer in Laboratory animals am Siedepunkt ist jedoch eine langsame oberflächliche zu. Ether: acute dermal toxicity test in the presence of –OH groups eyes, skin, kidneys, other! The breaking of the carbon-oxygen bond 111-76-2 Synonyms 2-butoxyethanol ; Butyl Cellosolve ; Butyl glycol use... With Presidential approval in 1991 the heart, and inhibition of endogenous respiration were observed in the body toxic! Review finds 2-butoxyethanol is a clear colorless liquid that smells like ether Wasser ein konstant bei 98,8 °C Azeotrop. Hydrogen Sulfide – added to the presence of the carbon-oxygen bond Consumer Products: Nachrichten aus der der. ”: glycol ethers the rabbit they should be collected in container a depends upon the dose,,. Question, provide feedback, or report a problem work being done,! To reduce exposures to ethylene glycol monobutyl ether acetate Cat No combination of with!